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I'm assuming you're using the most recent version of iSync (v1.3). Open iSync, click the Palm button, and check the settings. Do you have it set to sync all addresses, or just certain groups?
Does everything else (calendars, etc) work OK?
If I recall, the Palm address book application only lists one set of fields for address, not home and business. Change your custom fields to match your business address categories, and see if iSync is smart enough to figure it out.