They do have some differences....
A modem is available in the "Extreme" version, as is an external antenna port. Also, the "Extreme" version has a wired LAN port for handling wired network clients as well as wireless.
The "Express" version does not have these features, though it does have the audio port that the "Extreme" does not.
So, for you, since you also want to connect a machine without wireless support, I would go with the "Extreme" version.