You won't have any luck with a PC card. While ATI does make Mac drivers for their cards, there are instructions that are hard coded on the card itself that make it incompatible.
The way around that is for video card makers to manufacture their cards with a 'flashable' ROM. The Voodoo cards used to do this but I don't believe ATI ever has. Unfortunately, Voodoo cards are currently unsupported under OS X, so you won't get any 3-D acceleration.
Try and find a old Radeon card. ATI just released their new ATI Radeon chipset, so you should be able to find a closeout price on the older Mac card once the new card is available for the Mac. And the Radeon comes with a VGA adaptor...