well...
i have no idea, how to author a "mix media" dvd, which plays back dvd on a dvd player PLUS offers some "computer files". yes, you can buy such dvds, but how to that on a mac - no idea.
BUT:
of course, you can save different versions of your movie on a data cd/dvd; and you could save a VIDEO_TS file, which the engaged pc user could start on his machine....-
btw: s-vcd is a standard, which allows to burn on a cheap cd-rom video in a much better quality than vcd; use google to find some infos; the best authering tool for constructing s_vcds with menus is video buidler (versiontracker)
again: you can't produce s-vcds with mixed tracks (data plus video)
how about producing a website? use your favorite website designer tool ( i do like freeway, they offer for free a 30 day evalution version!!), place your videos (quicktime, probabyl diffenrent versions in different quality) on the site and safe the project on a disc.
so, every user, pc or mac, navigator or safari, could open this "local" website, it looks good and they can watch the videos in a quality tehy want to.
just an idea.....