I've not tried it but I suspect the Aja and Blackmagic cards will
not work with FC Express. Third-party card support is
listed as a pro-only feature by Apple. I'm guessing that since FCE doesn't support uncompressed video, it's unlikely that the manufacturers would bother supporting FCE as part of their target market.
If you just want to capture/playout DV from/to SDI, you might be able to pick up an old
Miranda DV-bridge for cheap.