You can change your login password, but there apparently is no way to change a "forgotten" master password once you've set it.
Still, it only takes your login password to turn off Filevault. So you turn off filevault.
Now, you can delete the master password. It's in your keychain access, and to delete it you use the login password. Then you can go to System Prefs and set new master password.
Any previous filevault that you've created with the "forgotten" password will still use the "forgotten" password.
Many people recommend using an encrypted disk image to store your sensitive docs rather than using filevault.