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It's fine. The wattage rating just refers to the maximum output power. You could use the 45W adapter with a MacBook Pro, but it would take forever and a half to charge.
I think the MBA Magsafe plug points out at a slightly odd angle; you might find you need to sit the computer up on a magazine or something, just thick enough to make sure that the larger Magsafe plugs of other portables can clear the desk top.