Actually, on most PowerBooks (up to the G3 Wallstreet series) you have just one of these serial ports (modem and printer port combined into one socket), on beige Macs up to G3 you have two of these ports.
The printer port with these Macs is not exactly a RS-232, but a RS-422 port usable for Appletalk networking, too. But a RS-422 can do anything a RS-232 can, it is just more capable.
In some situations to use the printer port as a plain RS-232 (e.g., for connecting a modem) you need to turn AppleTalk off.
Walter.