Choose the "Customize Menu..." option in the Input Menu (the one with the flag; or go to System Preferences -> International -> Input Menu) and add "U.S. Extended" to your available layouts. Now, go back to the app you wanted the macron'd letter in, and switch to "U.S. Extended" via the Input Menu. Type option-a, and then the letter you want the macron over. e.g., option-a then o types ō (hope that shows up here).
HTH.