Three reasons, none of which are really scientific, but oh well:
1. It just seems to make sense to use the format that's designed for CD images, the CD/DVD Master format.
2. For some reason, I've had a bunch of people with images that just wouldn't boot and then they worked after they converted the image to CD/DVD Master with Disk Utility. I have no idea why. Also, I seem to have noticed fewer of these types of reports after doing the switch (although it could be placebo effect).
3. This cuts down on people burning the .dmg file that BootCD came on and then wondering why it didn't boot. You might not believe it, but I really
did get this kind of problem report a bunch of times.
