You can also do this on a file-by-file basis if you want some files to open with a particular application and the rest with the default app. Just right/control click on the specific file, and when the contextual menu pops up, hold down the option key and 'Open with...' changes to 'Always open with...'
Pick the app you want to use and that particular file will open using that app, while the rest are associated with the default app.