10-50 shots per session and only moving a few hundred pix from the PC is very few for typical DSLR capture. At those kinds of volumes you need not consider RAID. RAID requires multiple drives configured in arrays and IMO you do not yet need that step.
"Scratch" is a working file that PS opens concurrent with every PS file you open. PS reads/writes constantly to that file even when you have lots of RAM. Under PSCS3 Preferences you assign where PS will assign scratch to. For good performance primary scratch should be on a different physical drive (drive partitions mean nothing and are not recommended) than the OS and app are on.
I suggest for your described needs:
Drive A: OS and apps
Drive B: scratch and images
Drive C: Onsite backup
IMO larger is better as regards drive size. Less full drives are faster because drives slow down as they fill. Not exceeding 70% full is a good rule of thumb. I would add 1TB sized drives all identical, which would also make any future RAID configurations easier to implement.
Some folks recommend discount drives but I do not. Cheap often means lesser OEM quality and/or last generation tech. I buy from OWC:
Find the latest Performance Upgrades, Firewire and USB Hard Drives, SATA, Memory, Laptop Battery, and more at OWC. Working with typical DSLR captures anecdotal information suggests that the 32 MB buffers of better modern enterprise-class drives may improve performance.
Moving a few hundred images I suggest burning to DVD, which gives a hard backup to move off site as part of the process.
HTH
-Allen Wicks