I used a later-generation battery in my TiBook, and it worked perfectly, with the added bonus of extra battery life. Apple usually phases out the older batteries and sells the new ones as extras for all PowerBooks in the line. For example, with the 1GHz/867MHz TiBooks, the new battery was the only one offered as a replacement, and it was compatible with all TiBooks that came before it despite having greater energy capacity.
Due to improvements in battery technology, the capacity goes up, but Apple doesn't change the external physical aspects of the battery. So based on past history, the new batteries will work fine.